Fluid metals

Most materials, when heated to temperatures exceeding a few thoudand Kelvin, become fluid metals composed of ions and degenerate electrons. We have been conducting fundamental researches on the properties of "warm dense matter" located between low-temperature solids and hot ionzized gases.

When an expanding liquid metal enters the gas phase through the supercritical state, electrons are eventually localized at each atomic site, exhibiting a metal-nonmetal transition. By combining quantum-chemical analysis of clusters and statistical theory of liquids, we have succesfully reproduced the gas-liquid coexistence curve and critical point of mercury from first principles (see the figure below).

Quantum dynamics of electrons in fluid metals is also a subject of great significance in relation to x-ray scattering experiments.



Fig. 1: Gas-liquid coexistence curve of mercury on the mass density-temperature plane.

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